(I almost put Deadpool in the list but he still do evil stuff in the comics)
Juggernaut has been a long time villain of the X-men, He is not a mutant but he got powers because of some magical gem. He is Professor X's brother. Recently he got a change of heart and is a member of X-men now.

Magneto has become leader of X-men at certain point and currently an active member. He became evil because want to protect mutants from racist humans.

Rouge started as a teenage supervillain who does everything Mystique tells her. She debuted as a villain of the Avengers. She almost killed Captain America, Stole Captain Marvel's power and beats up every single Avenger who is not Hulk. She changed her ways when X-men tries to make her join them. Here she is stealing Captain Marvel's powers on her Miss Marvel days.

Venom: He is a villain to Spiderman but he fights crime these days.

DC:
Catwoman- if you think about it, she is not that evil, She is a Thief who uses her loot to help stray cats and endangered big cats like lions and tigers. Her encounters with Batman made her change her ways.

Harley Quinn

Many people are able to relate to her when she was Joker's girlfriend because she is a martyr in an abusive relationship. Ever since she was put in Suicide Squad, she is becoming less and less villainous and currently the best selling female character in DC, She sells more comics than Wonder woman.







